腺嘌呤基生物金属有机框架是近年发展起来的一类新型金属有机框架材料,其多孔性和结构多样性使其在各个应用领域都有所建树,如气体吸附与分离,而腺嘌呤作为核碱基的一种更是赋予了金属有机框架材料良好的生物相容性,在医学领域有很好的应用前景。总结了近年来腺嘌呤作为有机配体或修饰材料组装成的金属有机框架材料在气体吸附与分离、催化、医学等领域的应用,并展望其研究前景。
Adenine based biometallic organic framework is a new kind of metal organic framework materials developed in recent years.Their porous and structural diversity make them have achievements in various application fields,such as gas adsorption and separation.Adenine,as a kind of nuclear base,endows metal organic frameworks of good biocompatibility and has a good application prospects for the field of medicine.The recent applications of metal organic frameworks assembled by adenine as organic ligands or modified materials in gas adsorption and separation,catalysis,medicine and other fields were summarized,and prospected the research prospects.
[1] Cai H,Xu L L,Li M,et al.Coordination chemistry and supramolecular recognition of adenine biometallic organic frameworks[J].Chinese Science Bulletin,2016,61(16):1762-1773.
[2] Wan X R,Zhang Z B.Climate warming and humans played different roles in triggering Late Quaternary extinctions in east and west Eurasia[J].Proceedings of the Royal society B:Biological Sciences,2017,284(1851):20162438.
[3] Nicola G,Antonio P,Denenico C.MOF-based adsorbents for atmospheric emission control:a review[J].Processes,2020,8(5):613-634.
[4] Jiang L,Gonzalez-Diaz A,Ling-Chin J,et al.Post-combustion CO2 capture from a natural gas combined cycle power plant using activated carbon adsorption[J].Applied Energy,2019,245:1-15.
[5] Nicola G,Shibata K,Antonio P,et al.Reinventing rice husk ash:derived NaX zeolite as a high-performing CO2 adsorbent[J].International Journal of Environmental Science & Technology,2018,15:1543-1550.
[6] Ghanbari T,Abnisa F,Daud W M A W.A review on production of metal organic frameworks(MOF) for CO2 adsorption[J].Science of the Total Environment,2020,707:135090.
[7] Mason J A,Sumida K,Herm Z R,et al.Evaluating metal-organic frameworks for post-combustion carbon dioxide capture via temperature swing adsorption[J].Energy & Environmental Science:EES,2011,4:30303040.
[8] Bao Z B,Yu L,Ren Q L,et al.Adsorption of CO2 and CH4 on a magnesium-based metal organic framework[J].Journal of Colloid & Interface Science,2011,353:549556.
[9] Herm Z R,Krishna R,Long J R.CO2/CH4,CH4/H2 and CO2/CH4/H2 separations at high pressures using Mg2(dobdc)[J].Microporous and Mesoporous Materials,2012,151:481487.
[10] Remy T,Peter S A,Perre S V D,et al.Selective dynamic CO2 separations on Mg-MOF-74 at low pressures:adetailed comparison with 13X[J].Journal of Physical Chemistry C,2013,117:9301-9310.
[11] Atci E,Erucar I,Keskin S.Adsorption and transport of CH4,CO2,H2 mixtures in a bio-MOF material from molecular simulations[J].Journal of Physical Chemistry C,2011,115:68336840.
[12] Burneo I,Stylianou K C,Rodríguez-Hermida S,et al.Two new adenine-based Co(Ⅱ) coordination polymers:synthesis,crystal structure,coordination modes and reversible hydrochromic behavior[J].Crystal Growth & Design,2015,15(7):3182-3189.
[13] Fu H R,Zhang J.Flexible porous zinc-pyrazole-adenine framework for hysteretic sorption of light hydrocarbons[J].Crystal Growth & Design,2015,15(3):1210-1213.
[14] Ishaq S,Tamime R,Bilad M R,et al.Mixed matrix membranes comprising of polysulfone and microporous Bio-MOF-1:Preparation and gas separation properties[J].Separation and Purification Technology,2019,210:442-451.
[15] Maity R,Singh H D,Yadav A K,et al.Water-stable adenine-based MOFs with polar pores for selective CO2 capture[J].Chemistry - an Asian Journal,2019,14(20):3736-3741.
[16] Ding M L,Robinson W F,Jiang H L,et al.Carbon capture and conversion using metal-organic frameworks and MOF-based materials[J].Chemical Society Reviews,2019,48:2783-2828.
[17] Huang Y B,Liang J,Wang X S,et al.Multifunctional metal-organic framework catalysts:synergistic catalysis and tandem reactions[J].Chemical Society Reviews,2017,46(1):126-157.
[18] Vermoortele F,Ameloot R,Vimont A,et al.An amino-modified Zr-terephthalate metal-organic framework as an acid-base catalyst for cross-aldol condensation[J].Chemical Communications,2011,47(5):1521-1523.
[19] Yang Y,Yao H F,Xi F G,et al.Amino-functionalized Zr(Ⅳ) metal-organic framework as bifunctional acid-base catalyst for knoevenagel condensation[J].Molecular Catalysis,2014,390:198-205.
[20] Rasero-Almansa A M,Corma A,Iglesias M,et al.Design of a bifunctional Ir-Zr based metal-organic framework heterogeneous catalyst for the N-alkylation of amines with alcohols[J].ChemCatChem,2014,6(6):1794-1800.
[21] Wu P Y,Wang J,Li Y M,et al.Luminescent sensing and catalytic performances of a multifunctional lanthanide-organic framework comprising a triphenylamine moiety[J].Advanced Functional Materials,2011,21(14):2788-2794.
[22] Kathalikkattil A C,Babu R,Roshan R K,et al.An lcy-topology amino acid MOF as eco-friendly catalyst for cyclic carbonate synthesis from CO2:structure-DFT corroborated study[J].Journal of Materials Chemistry A Materials for Energy & Sustainability,2015,3(45):22636-22647.
[23] Tran U P N,Le K K A,Phan N T S.Expanding applications of metal-organic frameworks:zeolite imidazolate framework ZIF-8 as an efficient heterogeneous catalyst for the knoevenagel reaction[J].ACS Catalysis,2011,1(2):120-127.
[24] Luan Y,Qi Y,Gao H Y,et al.A general post-synthetic modification approach of amino-tagged metal-organic frameworks to access efficient catalysts for the Knoevenagel condensation reaction[J].Journal of Materials Chemistry A,2015,3(33):17320-17331.
[25] Zhang S X,He H M,Sun F X,et al.A novel adenine-based zinc(Ⅱ) metal-organic framework featuring the Lewis basic sites for heterogeneous catalysis[J].Inorganic Chemistry Communication,2017,79:55-59.
[26] Azhar M R,Vijay P,Tade M O,et al.Submicron sized water-stable metal organic framework (bio-MOF-11) for catalytic degradation of pharmaceuticals and personal care products[J].Chemosphere,2018,196:105-114.
[27] Rachuri Y,Kurisingal J F,Chitumalla R K,et al.Adenine-based Zn(Ⅱ)/Cd(Ⅱ) metal-organic frameworks as efficient heterogeneous catalysts for facile CO2 fixation into cyclic carbonates:a DFT-supported study of the reaction mechanism[J].Inorganic Chemistry,2019,58(17):11389-11403.
[28] Feng C,Qiao S S,Guo Y,et al.Adenine-assisted synthesis of functionalized F-Mn-MOF-74 as an efficient catalyst with enhanced catalytic activity for the cycloaddition of carbon dioxide[J].Colloids and Surfaces A Physicochemical and Engineering Aspects,2020,597:124781.
[29] Sun R W Y,Zhang M,Li D,et al.Dinuclear gold(Ⅰ) pyrrolidinedithiocarbamato complex:cytotoxic and antimigratory activities on cancer cells and the use of metal-organic framework[J].Chemistry European Journal,2015,21(51):18534-18538.
[30] Bang D Y,Lee I K,Lee B M.Toxicological characterization of phthalic acid[J].Toxicological research,2011,27(4):191-203.
[31] Lin W X,Hu Q,Yu J C,et al.Low cytotoxic metal-organic frameworks as temperature-responsive drug carriers[J].Chempluschem,2016,81(8):804-810.
[32] Oh Hyojae,Li T,An J.Drug release properties of a series of adenine-based metal-organic frameworks[J].Chemistry European Journal,2015,21(47):17010-17015.
[33] An J,Geib S J,Rosi N L.Cation-triggered drug release from a porous zinc-adeninate metal-organic framework[J].Journal of the American Chemical Society,2009,131(24):8376-8377.
[34] An J,Farha O K,Hupp J T,et al.Metal-adeninate vertices for the construction of an exceptionally porous metal-organic framework[J].Nature Communications,2012,3:604-610.
[35] Li T,Kozlowski M T,Doud E A,et al.Stepwise ligand exchange for the preparation of a family of mesoporous MOFs[J].Journal of the American Chemical Society,2013,135(32):11688-11691.
[36] Liu W,Yan Z J,Zhang Z,et al.Bioactive and anti-corrosive bio-MOF-1 coating on magnesium alloy for bone repair application[J].Journal of Alloys and Compounds,2019,788:705-711.
[37] Cai H,Lu W G,Yang C,et al.Tandem förster resonance energy transfer induced luminescent ratiometric thermometry in dye-encapsulated biological metal-organic frameworks[J].Advanced Optical Materials,2019,7:1801149.
[38] Jonckheere D,Coutino-Gonzalez E,Baekelant W,et al.Silver-induced reconstruction of an adeninate-based metal-organic framework for encapsulation of luminescent adenine-stabilized silver clusters[J].Journal of Materials Chemistry C Materials for Optical & Electronic Devices,2016,4:4259-4268.
[39] Rachuri Y,Parmar B,Bisht K K,et al.Multiresponsive adenine-based luminescent Zn(Ⅱ) coordination polymer for detection of Hg2+ and trinitrophenol in aqueous media[J].Crystal Growth & Design,2017,17(3):1363-1372.
[40] Chen R F,Yao Z X,Han N,et al.Insights into the adsorption of VOCs on a cobalt-adeninate metal-organic framework (bio-MOF-11)[J].ACS Omega,2020,5(25):15402-15408.
基金资助
广州市科技计划项目(201904010087)
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